Radiation-chemical Oxidation of Peptides in the Solid State.

نویسندگان

  • W M GARRISON
  • M E JAYKO
  • W BENNETT-CORNIEA
چکیده

Gamma-ray irradiation of polypeptides as highly dispersed fluffs under oxygen leads to chemical degradation of the peptide bond with the remarkably high oxygen consumption of about one molecule per 2 ev of absorbed energy. A radical chain mechanism appears to be involved, and there is evidence that excited states of the polypeptide aggregate undergo chemical quenching by molecular oxygen.

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عنوان ژورنال:
  • Science

دوره 146 3641  شماره 

صفحات  -

تاریخ انتشار 1964